| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Andrew K. Tibandebage | Ambassador | 1961 - 1968 |
| 2 | H.E. Chief David Kidaha Makwaia | Ambassador | 1969 - 1987 |
| 3 | H.E. Nicholaus Maro | Ambassador | 1987 - 1991 |
| 4 | H.E. Alfred Cyril Tandau | Ambassador | 1995 - 1997 |
| 5 | H.E. Brig. Gen. (Ret) Fransic Mndolwa | Ambassador | 2003 - 2010 |
| 6 | H.E. Dr. James M. Nzagi | Ambassador | 2010 - 2015 |
| 7 | H.E. Rajab Hassan Gamaha | Ambassador | 2015 - 2019 |
| 8 | H.E. Dr. Jilly Maleko | Ambassador | 2019 - 2023 |
